Sulfides
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Chimneys made of sulfide minerals form around focused hydrothermal vents. The composition of the chimneys depends on the composition of the vent fluids. As a chimney structure ages and continues to grow, some conduits become sealed off while others grow anew. Flanges and spires form in response to changing fluid flow patterns within the chimney, creating beautiful, delicate, and sometimes astonishingly large edifices. Sulfide chimneys exist at Castle, ASHES, and CASM in the NeMO study area. Some sulfide chimneys reach over 10 meters in height. Eventually the structures become unstable and fall, resulting in piles of sulfide rubble at the base of many chimneys. However, chimneys can grow back very rapidly, some at upwards of a meter per day! Chimney growth often begins with anhydrite precipitating in a zone of high temperature mixing between the vent fluid and the surrounding seawater. The anhydrite structure grows upward like a collar around the venting fluid stream. As the chimney evolves, hydrothermal fluid begins to diffuse out horizontally through the porous anhydrite walls. A copper-iron sulfide lining (such as chalcopyrite) is typically deposited on the inner walls of the chimney. Then as horizontal fluid flow continues, a gradual inward-thickening of the walls takes place with partial replacement of the original anhydrite with sulfide, and outward deposition of predominantly zinc-sulfides. |
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